Ed Wood from Ed Wood and real life.
He was not afraid to be who he wanted to be, make things that no one wanted, wear women's clothing in an era when that was deemed sissy behavior, and he took care of aging Bela Lugosi to give him one last hurrah in film.
Also, Harry Tuttle from Brazil. In and out sans red tape, treated everyone he met as a human being, fought against the inhuman and inordinate delays of a hyper capitalist totalitarian society to take back peace of mind for the impoverished.
And Queen Emeraldas. She's a space pirate from Galaxy Express 999 and Captain Harlock. She has a scar across her face, randomly shows up with brute force to challenge robots and save Maetel and Tochiro/Tetsuro. She is a space pirate who fights robots and has her own space pirate ship.