That moment when Podcastin' turned to its Paypal-based fundraisin' marathon and an earnest Gary St. Cloud started to tell the audience how hard it was doing the podcast, and how much work he and and Roy Hubbard put into it - right before Tom himself completely lost it - that was sublime.
But somehow, not my favorite moment of the show! That would be during the Spike call, when some loud music started randomly playing on Spike's end, and Tom asked him "What was that, your wrist watch?"
Also, I can't remember the context (maybe it was to Mike?), but there was a great moment where Tom went from perfectly cordial to threatening "I'll throw you off a ROOF!" in about half of a second, and immediately back to pleasant conversation again. What an episode!